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| For those of you who cannot get enough technical information, this is the area describing the production of titanium in excruciating detail. |
| - Production of
Titanium tubing from Rutile Ore (Ti02) Titanium is the fourth most abundant structural element on earth, found usually in ores of ilenite and rutile, that contain anywhere from 40% to 95% titanium dioxide (TiO2). |
| A sponge must be developed in two steps. (Note:
the term sponge is used because it best describes the porous nature
of portions of the reduction mass.)
Step One (Getting the Titanium)
Titanium dioxide (TiO2) is mixed with coke or tar and charged in a chlorinator.
Heat and chlorine gas are applied. The titanium ore reacts with the
chlorine to form titanium tetrachloride (TiCl4). The output of the chlorination
process is a crude tetrachloride. Purification is necessary, and is
accomplished by a series of fractional distillation and condensation
steps. Titanium tetrachloride is reduced to metal by reaction with metallic
sodium or magnesium, or electrolysis with molten salt. The magnesium
reduction process invented by Dr. William Kroll is the most commonly
utilized method. Purified titanium tetrachloride (TiCl4) is metered
into a steel reaction vehicle with an exact quantity of pure magnesium.
The reaction vessel is sealed and evacuated to prevent atmospheric gases
from contaminating the mixture. Significant amounts of heat are added.
The magnesium melts, causing a reaction forming titanium metal and magnesium
chloride. When the reduction process is complete, residual magnesium
and magnesium chloride are removed from the metal mass. The resultant
is a sponge that may be chipped or machined out of the reduction vessel.
The sponge is crushed if necessary and sampled for chemical composition.
Care must be taken while melting the titanium, atmospheric gases and
nearly all refractory materials contaminate the molten metal. In the
consumable electrode process, sponge titanium is blended with alloying
constituents and compacted in large hydraulic presses to form briquettes
that are assembled into electrodes for melting. The electrode is attached
to a water cooled ram to provide vertical movement in the vacuum furnace
and carry the current to the electrode. Volatile materials are removed
during the initial melting operations. The re-melted materials are formed
into an ingot weighing close to five (5) tons.
Step Two (Making the Titanium Tubing)
Conversion of the ingot into an extruded hollow is accomplished through
hot working techniques and equipment. The ingot is heated and forged
in a series of reductions until a bar (approximately 8 inches in diameter)
is achieved. Finish temperatures are closely regulated to establish
optimum grain size and phase distribution. Cold working reduces the
extruded hollow tube to the final tube size. (Cold reduction can be
made using swaging, drawing, and tube reducing. The most common method
is tube reducing (pilgering or rocking). Reductions of approximately
60 - 70% are regularly used between annealing steps. Numerous additional
steps are required to gradually bring the tubing down to the desired
diameter. Tube reducing is one of the most critical steps because crystallographic
texture, grain size, and other metallurgical properties are developed
during this stage. Tubing used by DEAN is processed using conventional
and proprietary practices unique in the industry. The differences allow
the optimum crystallographic textures and mechanical properties to be
exploited for specific needs in biking. |